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bond Thus, attachment of a proton or other Lewis acid would occur at the oxygen atom, in the plane of the carbonyl group, and more or less perpendicular to the C O bond In Figure 322, we show the interaction of the nO and sH orbitals in the most natural geometry, with the newly formed s bond horizontally disposed Notice that we have reoriented the molecular framework and all of the orbitals into the same orientation from the one in Figure 321 This reorientation does not a ect the orbital energies Notice that the line of approach for the HOMO LUMO interaction brings the proton in approximately along the nodal surfaces of all of the other orbitals, so in the rst instance all other possible interactions will be small and can be ignored To make this point, Figure 3.

8.4 PACS NETWORK DESIGN PACS networks should be designed as an internal network (within the PACS) with connections to external networks such as the manufacturer s imaging network, radiology information network, hospital information networks, or the enterprise networks. All network connections in blue shown in Figure 8.2 are PACS network except those going outside of the PACS domain like the HIS/RIS application servers and Web servers, which are in orange. The security of external networks is the responsibility of the hospital and the enterprise network authority, the security of the imaging modalities network is the responsibility of the manufacturer s imaging network manager, and PACS internal network security is the responsibility of the PACS administration. The PACS internal network should only be accessible through layers of security measures assigned by the PACS manager. 8.4.1 External Networks This section describes types of external networks that can be connected to the PACS network. 8.4.1.1 Manufacturer s Image Acquisition Device Network Major imaging manufacturers have their own networks for connecting several imaging devices

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22 is far more cluttered than it needed to be since only the orbitals connected by the interaction lines needed to be shown This diagram shows only the initial interaction as would be suitable for formation of a hydrogen bond If the proton were to become attached, the sOH orbital would be much lower in energy and the sOH much higher Since the donor orbital is nonbonding, addition of the Lewis acid to the oxygen is not accompanied by loss of either the s or p bond In this gure, we have ignored the e ect of the charge We will see in s 5 and 8 that the net charge does have a dramatic e ect on the remaining orbitals We can also crudely estimate the basicity of the carbonyl oxygen atom.

cannot only provide near uniform chemical composition but also energy content. A comparison of heating values of municipal waste with various other waste fuels and biomass is given in Table 15.2. The data shows that the energy content in the MSW is comparable with some wood material and wastes. The energy associated with plastics is very high as compared to nonplastic wastes. The composition of the solid waste has been changing over the past two decades. This is because of the changing needs of the society as well as some of the process and manufacturing needs and re nements. Table 15.3 shows the immediate past, present, and near-term projected refuse composition. Irrespective of the type and amount of waste, the amount of wastes generated has been growing. From the energy availability there are signi cant opportunities.

Since the HOMO is strongly localized to the oxygen atom (the coe cient of 2 pO is close to 1), and the oxygen atom is monocoordinated but uncharged, one should expect the Lowry Bronsted basicity to be less than that of alkoxides, which are monocoordinated but charged Acidity or Electrophilicity The LUMO is a p-type orbital polarized toward the carbon atom (the coe cient of 2 pC is larger than the coe cient of 2 pO ) The LUMO is also relatively low in energy The low energy and large coe cient at carbon both suggest that the carbonyl group should be reactive as a Lewis acid or electrophile and that addition of nucleophiles (Lewis bases) would occur at the carbon atom and from a direction approximately perpendicular to the plane of the carbonyl group Figure 323 shows another way of applying orbital interaction theory.

Figure 12-17: CD being copied (track one has been recorded and track two is being recorded).

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