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Lombardi had disagreements with a number of the people who reported to him, as all leaders do And like most leaders, Lombardi had a few people who rebelled against his way of leadership They went somewhere else, and he stayed The interesting thing is that almost every one of his players, even the ones who left, still respected him

(a) Write reaction-equilibrium equations for each equation of the set State clearly any assumptions (b) Solve the set of equations to obtain algebraic expressions for the equilibrium vaporphase mole fractions of the four species in relation to the equilibrium constants, K I , K I I ,KIII (c) Use the data below to determine numerical values for the equilibrium constants at 500 K State clearly any assumptions (d) Determine numerical values for the mole fractions of the four species Species

In another reaction, 400 g of Cl2 and excess H2 are combined HCl will be produced How many grams of HCl will form H2(g) + Cl2(g) 2 HCl(g) 1 mol Cl 2 mol HCl 36461 g HCl 2 Answer: ( 400 g Cl 2 ) = 411 g HCl 70906 g Cl 2 1 mol Cl 2 1 mol HCl

A H&/J mol-' A GOf298/J mol-'

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W H AT I T TA K E S T O B E # 1

The simplest models for vaporlliquid equilibrium, based on Raoult's law and Henry's law, are presented in Chap 10, largely from an empirical point of view The calculations by modified Raoult's law, described in Sec 105, are adequate for many purposes, but are limited to low pressures The initial sections of this chapter therefore present two general calculational procedures for VLE, the first by an extension of modified Raoult's law and the second by equations of state The theoretical foundation for both procedures is presented in Chap 11 The remainder of this chapter deals more generally with phase equilibria, with consideration given in separate sections to liquidliquid, vaporlliquidliquid, solidlliquid, solidlvapor, adsorption, and osmotic equilibria

.

Modified Raoult's law includes the activity coefficientto account for liquid-phase nonidealities, but is limited by the assumption of vapor-phase ideality This is overcome by introduction of the vapor-phase fugacity coefficient For species i in a vapor mixture, Eq (1148) is written:

For species i in the liquid phase, Eq (1187) becomes:

When I think of him, Redskins offensive guard Ray Schoenke once said, I don t think of warmth I don t think of sensitivity If he was sensitive, he certainly wouldn t have said some of the things he said to me As much as I hated the guy, and I did I hated him! I had tremendous respect for him Tremendous I played some of my best football of my life under him It is a paradox Paradox is a concept that was introduced early in this book It is critical in understanding leadership And it s a word that comes up often when you speak to the people who worked with and for my father With calculation, he found ways to get you to do things you didn t know you were capable of doing

Equation (1144) requires these two expressions to be equal; whence,

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