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potential of the Ox1/Red1 couple (E0') at 50% titration, while it is equal to the for1 mal potential of the Ox2/Red2 couple (E0') at 200% titration. If we consider, for 2 simplicity, the case of n1 = n2 = n, the equilibrium constant of reaction (4.4), given by K = aOx1aRed2/(aRed1aOx2), is related to E0 and E0 by K = exp [(nF/RT)(E0 E0)]. The 1 2 2 1 increase in value of (E0 E0) increases the value of K and the redox reaction (4.4) 2 1 proceeds more completely to the right. Some typical redox couples and metal ion-metal couples are shown below, with the corresponding Nernst equations. The effects of solvents on these reactions will be discussed in the next section. 1. Mn ne 3 M M: metal 2

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For group and multiple requests, a number of additional factors have to be considered when discussing reliability: there may be more than one server and, furthermore, the middleware needs time to deliver the requests It is, therefore, rather likely that requests are not all delivered at the same time For the reliability of group and multiple requests we distinguish: 1 k-reliability, 2 totally ordered and 3 best effort K-reliability adds a second dimension to the at-least-once reliability that we discussed for unicast requests As with at-least-once reliability, the requested operations may have been executed more than once due to lost reply messages and care should be taken when using it with operations that modify server states The C O RBA Event service has been specialized into a Notification service, which has k-reliability semantics It achieves this by persistently storing requests in those cases where the event consumer is unavailable.

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testbed involves European NRENs and national testbeds, as well as G ANT2, crossborder dark fiber and GLIF infrastructures. A set of highly demanding applications will be adapted to prove the concept. Internationally, the project is a partner project to the US EnLIGHTened research project. Both projects will collaborate on developing a control plane for Grid computing research as well as extend functionality from each testbed to the other. The LUCIFER project is a large collaborative interdisciplinary research and testbed effort involving 20 partners from nine countries, including (a) NRENs, including CESNET (Czech Republic), PIONEIR (Poland), SURFnet (Netherlands; (b) national testbeds, including VIOLA, OptiCAT, and UKLight; (c) commercial companies, including ADVA, Hitachi, and Nortel; (d) SMEs, including NextWorks Consorzio Pisa Ricerche (CPR); and (d) research centers and universities, including Athens Information Technology Institute (AIT-Greece), Fraunhofer SCAI (Germany), Fraunhofer IMK (Germany), Fundaci i2CAT (Spain), IBBT (Belgium), RACTI (Greece), Research Centre J lich (Germany), University of Amsterdam (Netherlands), University of Bonn (Germany), University of Essex (UK), University of Wales-Swansea (UK), SARA (Netherlands), and non-EU participants, including MCNC (USA), and CCT@LSU (USA). The project is funded by the European Commission.

It is unlikelythat requests will be received simultaneouslybythe multiple servers involved In most cases, this does not cause further problems It might cause problems, however, if one request overtakes a request of an earlier cycle Totally ordered group and multiple requests are, therefore, always completed before the next group or multiple request can be started The C O RBA Event service achieves totally ordered requests This is done, however, at the expense of pushing an event through an event channel in a synchronous way Hence clients cannot continue before the last member of the group has executed the requested operation Best effort is the lowest degree of reliability No explicit measures are taken to guarantee a certain quality Best effort reliability is comparable to the maybe reliability that was introduced for unicast requests.

These may be attractive to small-scale retailers but are irrelevant to major retailers or small chains. Within the ranks of small retailers, those serving upper market levels will tend not to use them either. Why is this the case Each function will be examined in turn.

The multiple request primitives provided by C O RBA only achieve a best effort as they do not guarantee atomicity nor any order on the request delivery Having discussed these different degrees of reliability, we note a general trade-off between reliabilityand performance Achieving a high degree of reliabilityis veryinvolved It requires persistent storage of messages or the use of transactions, which are both rather time-consuming On the other hand, requests that may or may not have been executed can be dealt with veryquickly Onewayrequests in C O RBA do not require replymessages to be returned to the client and the client therefore does not need to synchronize with the server It is the task of the application designer to trade these different characteristics against each other in order to meet the mix of performance requirements that the stakeholders have specified..

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